Why won't Google index this new website?

Which Website? My first question is when you have launched your website. If it 2-3 days back then give it some time Google takes time to index new sites and make sure that your sitemap is uploaded and working properly (if not upload sitemap.xml). Also you can request Google crawl and fetch your site. for this can help you Ask Google to re-crawl your URLs.
 
Hi,
while getting crawled and indexed by search engine first time. it takes around 2-4 days in indexing. So don't, if still not indexed then you need to remove on-page errors to index your website.
 
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